YIKES!!! I'm really not at all sure what your true question was... something about why the Gateway defaults to 82.40.226.52. I'd assume it's getting that instruction from the ISP's DHCP server. But honestly your configuration is a mess!
First, why are you using OPEN VPN when SBS has a VPN included and is configured by running a simple wizard?
I'd recommend uninstalling it.
Then... remove ALL external DNS Server IPs from both NIC configurations. You should ONLY have the SBS's IP listed as a DNS Server... which apparently is 192.168.0.1
Add 192.168.0.1 as the WINS server on your internal NIC.
Disable NETBIOS over TCP/IP on your EXTERNAL NIC.
Ideally you should put a router between the external NIC and your Internet Connection... something simple like a D-Link 604 works well... as long as it provides VPN Passthrough to allow the SBS to get VPN connections properly.
What's the purpose of the persistent route? doesn't make sense to me
Finally Run the Configure Email and Internet Connection Wizard (CEICW -- linked as "Connect to the Internet on the To-Do list in the Server Management Console)
A visual how-to for that is here:
The CEICW ... and a full networking overview for SBS is at
How to configure Internet access in Windows Small Business Server 2003 with an example of a reasonable TWO NIC config here:
Two Nics, a static IP address, ISA, router
Sorry if all of that is too blunt... but you're wasting a lot of resource with this configuration.